The discussion below describes the current perceived front runner solution for the last stage decarbonisation of many grids which do not have huge hydro resources. It assumes no dramatic improvements in the economics of existing LDES (long duration energy storage) technologies. In the subsequent detail sections some of these assumptions are explored in more detail to present possible alternative solutions.
In the future, wind and solar generation are expected to dominate electricity supply in the majority of grids, with other forms of generation providing a much lower fraction of supply. However, wind and solar are variable and weather dependent, leading to periods of gaps in supply, split here into short duration gaps of less than a day and long duration gaps of a day up to a month or more.
Thus, affordable overgeneration (relative to total grid demand TWh per year) from wind and solar of 20-30%, will lead to periods with gaps in supply of, perhaps, 10-20% of grid demand, plus periods of surplus power.
Up to 8 hours of average load of grid battery storage is required to fill short duration gaps in wind and solar generation, depending on the proportion of flexible demand within total grid load. Some demand is flexible in when it must be met, and does not required battery smoothing to fill short duration gaps. This includes:-
The reason these loads can be supplied flexibly is that they incorporate their own forms of storage. In the case of EVs the storage is the EV battery itself. For heat pumps it is the phase change thermal store – which could be equally applicable for air conditioning systems.
Operating as flexible demand response loads, these devices can smooth some imbalances between grid demand and supply.
Note: although these particular flexible loads do not require short duration grid battery storage, their supply cannot necessarily be postponed indefinitely. In the case of a long duration gap in wind and solar, these demands must be satisfied from natural gas backup plants (in a pre-net zero grid) or long duration storage (typically green hydrogen storage and hydrogen fired CCGT or OCGT plants in a net zero grid).
The aim should be to provide sufficient short duration storage (/demand flexibility) to reduce the requirement for invoking long duration backup to less than 10% of supply.
Many mature grids have sufficient natural gas turbine generation to meet demand in the absence of adequate output from wind and solar generation. Once sufficient grid battery storage is installed to smooth over the short duration gaps, these natural gas turbine plants will be retained as backup plants to fill long duration gaps in wind and solar output, of a day up to a few weeks.
Thus, many grids may be able to reach 90% decarbonisation while continuing to use natural gas as a backup fuel.
To meet a grid net zero CO2 emissions target, the backup fuel must be switched from natural gas, to green hydrogen. The green hydrogen can be produced via electrolysis of water using surplus wind and solar power and stored underground in man-made salt caverns or depleted oil and gas wells.
CCGT (combined cycle gas turbine) or OCGT (open cycle gas turbine) natural gas generation plants can be converted to use green hydrogen by changing the burners and some other components. Safety systems must also be upgraded. Many recent gas turbines are designed to make the change from natural gas to hydrogen fuel more straightforward. For instance, some GE gas turbines can already take a fuel mix from 100% methane (natural gas) up to 100% hydrogen.
Some flexible loads may not require backup (or may require only partial backup) for long duration gaps. These include:-
In such processes, the stock of finished material produced substitutes for the some or all of the backup or long-duration storage required to ensure the necessary degree of reliability of supply applicable for this particular process.
Some grids are currently predominantly supplied by coal plants, such as in China. This section examines the differences.
When used as backup plants, the start up time difference between a gas and coal plant is very significant.
The following chart is from an article by Wärtsilä on the start up times for different types of gas generation.
The simple cycle gas turbines and combustion engines can reach full output in 20 minutes or less. CCGT (combined cycle gas turbine) plants have a secondary steam cycle using the heat exhaust from the primary gas turbine stages, and take up to 50 minutes to start up. Times vary depending on whether the plant is completely cold, or has been kept warm.
However, coal generation plants are very considerably slower to start up, but it depends on how long it has been since the previous generation stopped. For a coal plant which has not generated for 120 hours (5 days) or more, it can take 4-6 hours to bring a coal plant back to 25% output. Some of the issues are to do with technologies in place to limit SO2 and NOx emissions.
When used as the main backup in a predominantly wind and solar, coal plants will have to be scheduled very differently from gas plants, as they must be started hours in advance of when the backup generation is required.
In general, grids will be using weather forecasts for days in advance to determine when backup must be scheduled. The accuracy of such forecasts is good, and does not depend on whether gas or coal plants are used for backup.
The form of backup may determine how much grid battery storage is required to augment the backup generation.
For gas plants with start up times of less than an hour, then an hour duration of average load of grid battery storage is likely to be sufficient when combined with good weather forecasting.
However, if backup is from coal plants, then an hour of average load of grid batteries will be insufficient to remove the risk from occasional poor weather forecasting. Six hours may be more realistic.
At the point when a grid transitions to net zero emissions, fossil fuel backup plants have to be transitioned to green hydrogen backup or there must be some other form of zero emissions backup.
Gas turbine plants are likely to retain a similar efficiency when fueled by green hydrogen. Modern CCGT plants can achieve 60% efficiency, with Siemens claiming up to 64%. The conversion process to hydrogen fuel is relatively straightforward, involving replacing the burners and some other components.
However, coal plants typically have lower efficiencies – in the range of 33-47%.
To convert coal plants to use hydrogen fuel is more difficult than the conversion of gas plants.
In a single cycle, gas turbine generation plant, combustion of natural gas or green hydrogen directly drives the turbine blades. In a “combined cycle” gas turbine plant (CCGT) the process starts the same, but the waste heat from the first stage is then used to boil water to steam. A secondary power generation cycle uses this steam to generate power.
In most coal plants, the heat from fluidised bed combustion of coal is used in a boiler to produce steam, which is used in steam turbines to produce power. To convert to green hydrogen fuel would need some sort of boiler replacement or significant upgrade.
There seem to be differences of opinion on whether coal plants can be converted to green hydrogen firing.
Siemens believes it is not economic to modify most existing coal plants to use green hydrogen fuel.
However, Australian hydrogen R&D company Star Scientific claims to have developed a patented process for a HERO (Hydrogen Energy Release Optimiser) catalytic coating, which seems to enable a solid block of material to behave like hot coal when fed with hydrogen and air.
If coal plants cannot be converted economically to hydrogen firing, new gas or coal plants may have to replace existing coal plants. The front runner technology is combined cycle gas turbine plants optimised for hydrogen firing. However, hydrogen fuel cell technology is a further possibility, though it has a slightly lower efficiency at 60%, according to Siemens above.